Liquid crystal display device

ABSTRACT

The invention is to provide an AM device containing a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or that is suitably balanced regarding at least two of the characteristics, and having a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth, where the liquid crystal display device contains the liquid crystal composition that includes a specific compound having a large dielectric anisotropy as a first component and having positive dielectric anisotropy.

CROSS-REFERENCE TO RELATED APPLICATION

This application is a 371 of international application of PCT application serial no. PCT/JP2010/057748, filed on May 6, 2010, which claims the priority benefit of Japan application no. 2009-114248, filed on May 11, 2009. The entirety of each of the above-mentioned patent applications is hereby incorporated by reference herein and made a part of this specification.

FIELD OF THE INVENTION

The invention relates mainly to a liquid crystal composition suitable for use in an active matrix (AM) device and so forth, and an AM device and so forth that contains the composition. More specifically, the invention relates to a liquid crystal composition having positive dielectric anisotropy, and a device containing the composition and having a mode such as a twisted nematic (TN) mode, an optically compensated bend (OCB) mode, an in-plane switching (IPS) mode or a polymer sustained alignment (PSA) mode.

BACKGROUND OF THE INVENTION

In a liquid crystal display device, a classification based on an operating mode for liquid crystals includes modes of phase change (PC), twisted nematic (TN), super twisted nematic (STN), electrically controlled birefringence (ECB), optically compensated bend (OCB), in-plane switching (IPS), vertical alignment (VA) and polymer sustained alignment (PSA). A classification based on a driving mode in the device includes a passive matrix (PM) and an active matrix (AM). The PM is further classified into static, multiplex and so forth, and the AM is classified into a thin film transistor (TFT), a metal-insulator-metal (MIM) and so forth. The TFT is further classified into amorphous silicon and polycrystal silicon. The latter is classified into a high temperature type and a low temperature type according to the production process. A classification based on a light source includes a reflection type utilizing natural light, a transmission type utilizing a backlight and a semi-transmission type utilizing both natural light and a backlight.

These devices contain a liquid crystal composition having suitable characteristics. The liquid crystal composition has a nematic phase. General characteristics of the composition should be improved to give an AM device having good general characteristics. Table 1 below summarizes the relationship between the general characteristics of the two. The general characteristics of the composition will be explained further based on a commercially available AM device. The temperature range of a nematic phase relates to the temperature range in which the device can be used. A desirable maximum temperature of the nematic phase is approximately 70° C. or higher and a desirable minimum temperature of the nematic phase is approximately −10° C. or lower. The viscosity of the composition relates to the response time of the device. A short response time is desirable for displaying moving images on the device. Accordingly, a small viscosity of the composition is desirable. A small viscosity at a low temperature is more desirable.

TABLE 1 General Characteristics of Composition and AM Device General Characteristics General Characteristics No. of Composition of AM Device 1 wide temperature range wide usable temperature range of a nematic phase 2 small viscosity ¹⁾ short response time 3 suitable optical anisotropy large contrast ratio 4 large positive or negative low threshold voltage and small dielectric anisotropy electric power consumption large contrast ratio 5 large specific resistance large voltage holding ratio and large contrast ratio 6 high stability to ultraviolet long service life light and heat 7 large elastic constant short response time and large contrast ratio ¹⁾ A liquid crystal composition can be injected into a liquid crystal cell in a shorter period of time.

The optical anisotropy of the composition relates to the contrast ratio of the device. The product (Δn×d) of the optical anisotropy (Δn) of the composition and the cell gap (d) of the device is designed so as to maximize the contrast ratio. A suitable value of the product depends on the kinds of operating mode. In a device having a TN mode, a suitable value is approximately 0.45 micrometer. In this case, a composition having a large optical anisotropy is desirable for a device having a small cell gap. A large dielectric anisotropy of the composition contributes to a low threshold voltage, small electric power consumption and a large contrast ratio of the device. Accordingly, a large dielectric anisotropy is desirable. A large specific resistance of the composition contributes to a large voltage holding ratio and a large contrast ratio of the device. Accordingly, a composition having a large specific resistance is desirable at room temperature and also at temperatures close to the maximum temperature of a nematic phase in the initial stage. A composition having a large specific resistance is desirable at room temperature and also at temperatures close to the maximum temperature of a nematic phase after it has been used for a long time. The stability of the composition to ultraviolet light and heat relates to the service life of the liquid crystal display device. In the case where the stability is high, the device has a long service life. These characteristics are desirable for an AM device used in a liquid crystal projector, a liquid crystal television and so forth. A large elastic constant of the composition contributes to a short response time and a large contrast ratio. Accordingly, a large elastic constant is desirable.

A composition having positive dielectric anisotropy is used for an AM device having a TN mode. On the other hand, a composition having negative dielectric anisotropy is used for an AM device having a VA mode. A composition having positive or negative dielectric anisotropy is used for an AM device having an IPS mode. A composition having positive or negative dielectric anisotropy is used for an AM device having a PSA mode. Examples of liquid crystal compositions having positive dielectric anisotropy are disclosed in the following patent document.

PRIOR ART

Patent Document

Patent document No. 1: JP S57-154135 A (1982).

Patent document No. 2: JP S57-185230 A (1982).

Patent document No. 3: JP H02-233626 A (1990).

Patent document No. 4: JP H04-501575 A (1992).

Patent document No. 5: JP H04-501576 A (1992).

Patent document No. 6: JP H04-505477 A (1992).

Patent document No. 7: JP H05-105876 A (1993).

A desirable AM device has characteristics such as a wide temperature range in which the device can be used, a short response time, a large contrast ratio, a low threshold voltage, a large voltage holding ratio and a long service life. Response time that is even one millisecond shorter than that of the other devices is desirable. Thus, a composition having characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat is desirable.

OUTLINE OF THE INVENTION Subject to be Solved by the Invention

One of the aims of the invention is to provide a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat. Another aim is to provide a liquid crystal composition that is suitably balanced regarding at least two of the characteristics. A further aim is to provide a liquid crystal display device that contains such a composition. An additional aim is to provide a liquid crystal composition that has a large optical anisotropy, a large dielectric anisotropy, a high stability to ultraviolet light and so, forth, and is to provide an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth.

Means for Solving the Subject

The invention concerns a liquid crystal display device having a pair of substrates in which at least one of them is transparent, containing a liquid crystal composition sandwiched in between these substrates and having an alignment layer, a polarizing plate and a transparent electrode, wherein the liquid crystal composition has positive dielectric anisotropy and includes at least one compound selected from the group of compounds represented by formula (1) as a first component:

wherein R¹ is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring A is independently tetrahydropyran-2,5-diyl, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine; Z¹ is independently a single bond, ethylene or carbonyloxy; X¹ and X² are independently hydrogen or fluorine; Y′ is fluorine, chlorine or trifluoromethoxy; and m is 1, 2 or 3.

Effect Of The Invention

An advantage of the invention is a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat. One aspect of the invention is a liquid crystal composition that is suitably balanced regarding at least two of the characteristics. Another aspect is a liquid crystal display device that contains such a composition. A further aspect is a composition that has a large optical anisotropy, a large dielectric anisotropy, a high stability to ultraviolet light and so forth, and an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth.

EMBODIMENT TO CARRY OUT THE INVENTION

Usage of the terms in the specification and claims is as follows. The liquid crystal composition of the invention and the liquid crystal display device of the invention may be abbreviated to “the composition” and “the device,” respectively. “A liquid crystal display device” is a generic term for a liquid crystal display panel and a liquid crystal display module. “A liquid crystal compound” is a generic term for a compound having a liquid crystal phase such as a nematic phase or a smectic phase, and also for a compound having no liquid crystal phases but being useful as a component of a composition. Such a useful compound has a six-membered ring such as 1,4-cyclohexylene and 1,4-phenylene, and a rod-like molecular structure. An optically active compound and a polymerizable compound may occasionally be added to the composition. Even in the case where these compounds are liquid crystalline, the compounds are classified as an additive herein. At least one compound selected from the group of compounds represented by formula (1) may be abbreviated to “the compound (1).” “The compound (1)” means one compound, or two or more compounds represented by formula (1). The same rules apply to compounds represented by the other formulas. “Arbitrary” is used not only in cases where the position is arbitrary but also in cases where the number is arbitrary. However, it is not used in cases where the number is 0 (zero).

A higher limit of the temperature range of a nematic phase may be abbreviated to “the maximum temperature.” A lower limit of the temperature range of a nematic phase may be abbreviated to “the minimum temperature.” That “specific resistance is large” means that a composition has a large specific resistance at room temperature and also at a temperature close to the maximum temperature of a nematic phase in the initial stage, and that the composition has a large specific resistance at room temperature and also at a temperature close to the maximum temperature of a nematic phase even after it has been used for a long time. That “a voltage holding ratio is large” means that a device has a large voltage holding ratio at room temperature and also at a temperature close to the maximum temperature of a nematic phase in the initial stage, and that the device has a large voltage holding ratio at room temperature and also at a temperature close to the maximum temperature of a nematic phase even after it has been used for a long time. When characteristics such as optical anisotropy are explained, values which are obtained according to the measuring methods described in Examples will be used. A first component means one compound, or two or more compounds. “The ratio of the first component” is expressed as a percentage by weight (% by weight) of the first component based on the total weight of the liquid crystal composition. The same rule applies to the ratio of a second component and so forth. The ratio of an additive mixed with the composition is expressed as a percentage by weight (% by weight) or weight parts per million (ppm) based on the total weight of the liquid crystal composition.

The symbol R¹ is used for a plurality of compounds in the chemical formulas of component compounds. The meanings of R¹ may be the same or different in two arbitrary compounds among these. In one case, for example, R¹ of the compound (1-1) is ethyl and R¹ of the compound (1-7) is ethyl. In another case, R¹ of the compound (1-1) is ethyl and R¹ of the compound (1-7) is propyl. The same rule applies to the symbols R², R³ and so forth. In a chemical formula, “CL” stands for chlorine.

The invention includes the following items.

-   Item 1. A liquid crystal display device having a pair of substrates     in which at least one of them is transparent, containing a liquid     crystal composition sandwiched in between these substrates and     having an alignment layer, a polarizing plate and a transparent     electrode, wherein the liquid crystal composition has positive     dielectric anisotropy and includes at least one compound selected     from the group of compounds represented by formula (1) as a first     component:

wherein R¹ is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring A is independently tetrahydropyran-2,5-diyl, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine; Z¹ is independently a single bond, ethylene or carbonyloxy; X¹ and X² are independently hydrogen or fluorine; Y¹ is fluorine, chlorine or trifluoromethoxy; and m is 1, 2 or 3.

-   Item. 2. The liquid crystal display device according to item 1,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-1) to formula (1-41):

wherein R¹ is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.

-   Item 3. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-1). -   Item 4. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-7). -   Item 5. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-11). -   Item 6. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-12). -   Item 7. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-22). -   Item 8. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-23). -   Item 9. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-24). -   Item 10. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (1-34). -   Item 11. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is a     mixture of at least one compound selected from the group of     compounds represented by formula (1-1) and at least one compound     selected from the group of compounds represented by formula (1-7). -   Item 12. The liquid crystal display device according to item 2,     wherein the first component of the liquid crystal composition is a     mixture of at least one compound selected from the group of     compounds represented by formula (1-12) and at least one compound     selected from the group of compounds represented by formula (1-24). -   Item 13. The liquid crystal display device according to any one of     items 1 to 12, wherein the ratio of the first component of the     liquid crystal composition is in the range of 10% by weight to 70%     by weight based on the total weight of the liquid crystal     composition. -   Item 14. The liquid crystal display device according to any one of     items 1 to 13, wherein the liquid crystal composition further     includes at least one compound selected from the group of compounds     represented by formula (2) as a second component:

wherein R² and R³ are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring B and the ring C are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z² is independently a single bond, ethylene or carbonyloxy; and p is 1, 2 or 3.

-   Item 15. The liquid crystal display device according to item 14,     wherein the second component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (2-1) to formula (2-11):

wherein R² and R³ are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.

-   Item 16. The liquid crystal display device according to item 15,     wherein the second component of the liquid crystal composition is at     least one compound selected from the group of compounds represented     by formula (2-1). -   Item 17. The liquid crystal display device according to item 15,     wherein the second component of the liquid crystal composition is a     mixture of at least one compound selected from the group of     compounds represented by formula (2-1) and at least one compound     selected from the group of compounds represented by formula (2-5). -   Item 18. The liquid crystal display device according to item 15,     wherein the second component of the liquid crystal composition is a     mixture of at least one compound selected from the group of     compounds represented by formula (2-1) and at least one compound     selected from the group of compounds represented by formula (2-7). -   Item 19. The liquid crystal display device according to item 15,     wherein the second component of the liquid crystal composition is a     mixture of at least one compound selected from the group of     compounds represented by formula (2-1), at least one compound     selected from the group of compounds represented by formula (2-5)     and at least one compound selected from the group of compounds     represented by formula (2-7). -   Item 20. The liquid crystal display device according to any one of     items 14 to 19, wherein the ratio of the second component of the     liquid crystal composition is in the range of 30% by weight to 90%     by weight based on the total weight of the liquid crystal     composition. -   Item 21. The liquid crystal display device according to any one of     items 1 to 20, wherein an operating mode of the liquid crystal     display device is a TN mode, an OCB mode, an IPS mode or a PSA mode,     and a driving mode of the liquid crystal display device is an active     matrix mode.

Item 22. A liquid crystal composition contained in the liquid crystal display device according to any one of items 1 to 21.

-   Item 23. The liquid crystal composition according to item 22,     wherein the elastic constant (K) is 13 pN or more, and the ratio of     the elastic constant (K) to the viscosity (11) is 0.8 nN/Pa·s     (nm²/s) or more. -   Item 24. The liquid crystal composition according to item 22 or 23,     wherein the frequency dependence of the dielectric anisotropy [Δ∈(5     kHz)/Δ∈(50 Hz)] at −20° C. is 0.50 or more. -   Item 25. The liquid crystal composition according to any one of     items 22 to 24, wherein the maximum temperature of a nematic phase     is 70° C. or higher, the optical anisotropy (25° C.) at a wavelength     of 589 nanometers is 0.08 or more, and the dielectric anisotropy     (25° C.) at a frequency of 1 kHz is 2 or more. -   Item 26. The liquid crystal composition according to anyone of items     22 to 25, consisting essentially of the first component and the     second component. -   Item 27. Use of the liquid crystal composition according to any one     of items 22 to 26 in a liquid crystal display device.

The invention further includes the following items: (1) the composition described above, further including an optically active compound; (2) the composition described above, further including an additive, such as an antioxidant, an ultraviolet light absorber, an antifoaming agent, a polymerizable compound and/or a polymerization initiator; (3) an AM device containing the composition described above; (4) a device having a mode of TN, ECB, OCB, IPS or PSA and containing the composition described above; (5) a transmission-type device containing the composition described above; (6) use of the composition described above as a composition having a nematic phase; and (7) use as an optically active composition prepared by the addition of an optically active compound to the composition described above.

The composition of the invention will be explained in the following order. First, the constitution of component compounds in the composition will be explained. Second, main characteristics of the component compounds and main effects of these compounds on the composition will be explained. Third, a combination of components in the composition, desirable ratios of the component compounds and the basis thereof will be explained. Fourth, a desirable embodiment of the component compounds will be explained. Fifth, specific examples of the component compounds will be shown. Sixth, additives that may be mixed with the composition will be explained. Seventh, methods for synthesizing the component compounds will be explained. Last, use of the composition will be explained.

First, the constitution of component compounds in the composition will be explained. The compositions of the invention are classified into the composition A and the composition B. The composition A may further include any other liquid crystal compound, an additive and an impurity. “Any other liquid crystal compound” is a liquid crystal compound that is different from the compound (1) and the compound (2). Such a compound is mixed with the composition for the purpose of further adjusting characteristics of the composition. Of any other liquid crystal compound, a smaller amount of a cyano compound is desirable in view of its stability to heat or ultraviolet light. Amore desirable ratio of the cyano compound is 0% by weight. The additive includes an optically active compound, an antioxidant, an ultraviolet light absorber, a coloring matter, an antifoaming agent, a polymerizable compound and a polymerization initiator. The impurity is compounds and so forth which have contaminated component compounds in a process such as their synthesis. Even in the case where the compound is liquid crystalline, it is classified into the impurity herein.

The composition B consists essentially of compounds selected from the group of the compound (1) and the compound (2). The term “essentially” means that the composition may also include an additive and an impurity, but does not include any liquid crystal compound other than these compounds. The composition B has a smaller number of components than the composition A. The composition B is preferable to the composition A in view of cost reduction. The composition A is preferable to the composition B in view of the fact that physical properties can be further adjusted by adding any other liquid crystal compound.

Second, main characteristics of the component compounds and main effects of the compounds on the characteristics of the composition will be explained. The main characteristics of the component compounds are summarized in Table 2 on the basis of the effects of the invention. In Table 2, the symbol L stands for “large” or “high”, the symbol M stands for “medium”, and the symbol S stands for “small” or “low.” The symbols L, M and S are classified according to a qualitative comparison among the component compounds, and 0 (zero) means that “a value is nearly zero.”

TABLE 2 Characteristics of Compounds Compounds Compound (1) Compound (2) Maximum Temperature S-M S-L Viscosity M-L S-M Optical Anisotropy M-L S-L Dielectric Anisotropy S-L 0 Specific Resistance L L

Main effects of the component compounds on the characteristics of the composition upon mixing the component compounds with the composition are as follows. The compound (1) decreases the minimum temperature, and increases the dielectric anisotropy. The compound (2) increases the maximum temperature, or decreases the viscosity.

Third, a combination of the components in the composition, desirable ratios of the component compounds and the basis thereof will be explained. A combination of the components in the composition is the first component itself, and the first and second components. A combination of the components in the desirable composition is the first and second components.

A desirable ratio of the first component is approximately 10% by weight or more for decreasing the minimum temperature and for increasing the dielectric anisotropy, and approximately 70% by weight or less for decreasing the viscosity. A more desirable ratio is in the range of approximately 10% by weight to approximately 65% by weight. An especially desirable ratio is in the range of approximately 15% by weight to approximately 60% by weight.

A desirable ratio of the second component is approximately 30% by weight or more for increasing the maximum temperature or for decreasing the viscosity, and approximately 90% by weight or less for increasing the dielectric anisotropy. A more desirable ratio is in the range of approximately 35% by weight to approximately 85% by weight. An especially desirable ratio is in the range of approximately 40% by weight to approximately 80% by weight.

Fourth, a desirable embodiment of the component compounds will be explained. R¹, R² and R³ are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine. Desirable R¹ is alkyl having 1 to 12 carbons for increasing the stability to ultraviolet light or heat, for instance. Desirable R² or R³ is alkyl having 1 to 12 carbons for increasing the stability to ultraviolet light or heat, for instance.

Desirable alkyl is methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl or octyl. More desirable alkyl is ethyl, propyl, butyl, pentyl or heptyl for decreasing the viscosity.

Desirable alkoxy is methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy or heptyloxy. More desirable alkoxy is methoxy or ethoxy for decreasing the viscosity.

Desirable alkenyl is vinyl, 1-propenyl, 2-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl or 5-hexenyl. More desirable alkenyl is vinyl, 1-propenyl, 3-butenyl or 3-pentenyl for decreasing the viscosity. A desirable configuration of —CH═CH— in the alkenyl depends on the position of the double bond. Trans is preferable in the alkenyl such as 1-propenyl, 1-butenyl, 1-pentenyl, 1-hexenyl, 3-pentenyl and 3-hexenyl for decreasing the viscosity, for instance. Cis is preferable in the alkenyl such as 2-butenyl, 2-pentenyl and 2-hexenyl. In the alkenyl, straight-chain alkenyl is preferable to branched-chain alkenyl.

Desirable examples of alkenyl in which arbitrary hydrogen is replaced by fluorine are 2,2-difluorovinyl, 3,3-difluoro-2-propenyl, 4,4-difluoro-3-butenyl, 5,5-difluoro-4-pentenyl and 6,6-difluoro-5-hexenyl. More desirable examples are 2,2-difluorovinyl and 4,4-difluoro-3-butenyl for decreasing the viscosity.

The ring A is tetrahydropyran-2,5-diyl, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine, and arbitrary two of the ring A may be the same or different when m is 2 or 3. Desirable ring A is 1,4-phenylene for increasing the optical anisotropy. Tetrahydropyran-2,5-diyl is

and preferably

The ring B and the ring C are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene, and arbitrary two of the ring B may be the same or different when p is 2 or 3. Desirable ring B or ring C is 1,4-cyclohexylene for decreasing the viscosity, and 1,4-phenylene for increasing the optical anisotropy.

Z¹ and Z² are independently a single bond, ethylene or carbonyloxy, and arbitrary two of Z¹ may be the same or different when m is 2 or 3, and arbitrary two of Z² may be the same or different when p is 2 or 3. Desirable Z¹ or Z² is a single bond for decreasing the viscosity.

X¹ and X² are independently hydrogen or fluorine. Desirable X¹ or X² is fluorine for increasing the dielectric anisotropy.

Y¹ is fluorine, chlorine or trifluoromethoxy. Desirable Y¹ is fluorine for decreasing the minimum temperature.

m and p are independently 1, 2 or 3. Desirable m is 2 for decreasing the minimum temperature. Desirable p is 1 for decreasing the viscosity.

Fifth, specific examples of the component compounds will be shown. In the desirable compounds described below, R⁴ is straight-chain alkyl having 1 to 12 carbons. R⁵ is straight-chain alkyl having 1 to 12 carbons or straight-chain alkoxy having 1 to 12 carbons. R⁶ and R⁷ are independently straight-chain alkyl having 1 to 12 carbons or straight-chain alkenyl having 2 to 12 carbons. With regard to the configuration of 1,4-cyclohexylene in these compounds, trans is preferable to cis for increasing the maximum temperature.

Desirable compound (1) are the compound (1-1-1) to the compound (1-41-1). More desirable compound (1) are the compound (1-1-1), the compound (1-7-1), the compound (1-8-1), the compound (1-11-1), the compound (1-12-1), the compound (1-22-1), the compound (1-23-1), the compound (1-24-1), the compound (1-25-1), the compound (1-34-1) and the compound (1-39-1). Especially desirable compound (1) are the compound (1-1-1), the compound (1-7-1), the compound (1-11-1), the compound (1-12-1), the compound (1-22-1), the compound (1-23-1), the compound (1-24-1) and the compound (1-34-1). Desirable compound (2) are the compound (2-1-1) to the compound (2-11-1). More desirable compound (2) are the compound (2-1-1), the compound (2-3-1), the compound (2-5-1), the compound (2-7-1), the compound (2-8-1) and the compound (2-11-1). Especially desirable compound (2) are the compound (2-1-1), the compound (2-5-1), the compound (2-7-1) and the compound (2-11-1).

Sixth, additives which may be mixed with the composition will be explained. Such additives include an optically active compound, an antioxidant, an ultraviolet light absorber, a coloring matter, an antifoaming agent, a polymerizable compound and a polymerization initiator. The optically active compound is mixed with the composition for the purpose of inducing a helical structure and giving a twist angle in liquid crystals. Examples of such compounds include the compound (3-1) to the compound (3-4). A desirable ratio of the optically active compound is approximately 5% by weight or less, and a more desirable ratio is in the range of approximately 0.01% by weight to approximately 2% by weight.

An antioxidant is mixed with the composition in order to prevent a decrease in specific resistance that is caused by heating under air, or to maintain a large voltage holding ratio at room temperature and also at a temperature close to the maximum temperature of a nematic phase after the device has been used for a long time.

Desirable examples of the antioxidant include the compound (4) where n is an integer from 1 to 9. In the compound (4), desirable n is 1, 3, 5, 7 or 9. More desirable n is 1 or 7. The compound (4) where n is 1 is effective in preventing a decrease in specific resistance that is caused by heating under air, because it has a large volatility. The compound (4) where n is 7 is effective in maintaining a large voltage holding ratio at room temperature and also at a temperature close to the maximum temperature of a nematic phase even after the device has been used for a long time, because it has a small volatility. A desirable ratio of the antioxidant is approximately 50 ppm or more for achieving its effect and is approximately 600 ppm or less for avoiding a decrease in the maximum temperature or avoiding an increase in the minimum temperature. A more desirable ratio is in the range of approximately 100 ppm to approximately 300 ppm.

Desirable examples of the ultraviolet light absorber include a benzophenone derivative, a benzoate derivative and a triazole derivative. A light stabilizer such as an amine having steric hindrance is also desirable. A desirable ratio of the ultraviolet light absorber or the light stabilizer is approximately 50 ppm or more for achieving its effect and is approximately 10,000 ppm or less for avoiding a decrease in the maximum temperature or avoiding an increase in the minimum temperature. A more desirable ratio is in the range of approximately 100 ppm to approximately 10,000 ppm.

A dichroic dye such as an azo dye or an anthraquinone dye is mixed with the composition for adjusting to a device having a guest host (GH) mode. A desirable ratio of the coloring matter is in the range of approximately 0.01% by weight to approximately 10% by weight. An antifoaming agent such as dimethyl silicone oil or methyl phenyl silicone oil is mixed with the composition for preventing foam formation. A desirable ratio of the antifoaming agent is approximately 1 ppm or more for achieving its effect and is approximately 1,000 ppm or less for avoiding a poor display. A more desirable ratio is in the range of approximately 1 ppm to approximately 500 ppm.

A polymerizable compound is mixed with the composition for adjusting to a device having a polymer sustained alignment (PSA) mode. Desirable examples of the polymerizable compound include compounds having a polymerizable group, such as acrylates, methacrylates, vinyl compounds, vinyloxy compounds, propenyl ethers, epoxy compounds (oxiranes, oxetanes) and vinyl ketones. Especially desirable examples of the polymerizable compound are acrylate derivatives or methacrylate derivatives. A desirable ratio of the polymerizable compound is approximately 0.05% by weight or more for achieving its effect and is approximately 10% by weight or less for avoiding a poor display. A more desirable ratio is in the range of approximately 0.1% by weight to approximately 2% by weight. The polymerizable compound is polymerized on irradiation with ultraviolet light or the like, preferably in the presence of a suitable initiator such as a photopolymerization initiator. Suitable conditions for polymerization, suitable types of the initiator and suitable amounts thereof are known to a person skilled in the art and are described in the literature. For example, Irgacure 651 (registered trademark), Irgacure 184 (registered trademark) or Darocure 1173 (registered trademark) (Ciba Japan K.K.), each of which is a photoinitiator, is suitable for radical polymerization. The polymerizable compound includes the photopolymerization initiator preferably in the range of approximately 0.1% by weight to approximately 5% by weight and most preferably in the range of approximately 1% by weight to approximately 3% by weight.

Seventh, methods for synthesizing the component compounds will be explained. These compounds can be synthesized by known methods. The synthetic methods will be exemplified as follows. The compound (1-11-1) is prepared by the method described in JP S57-154135 A (1982). The compound (1-23-1) is prepared by the method described in JP S57-185230 A (1982). The compound (1-12-1) and the compound (1-24-1) are prepared by the method described in JP H02-233626 A (1990). The compound (2-1-1) and the compound (2-5-1) are prepared by the method described in JP S59-176221 A (1984). An antioxidant is commercially available. The compound with formula (4) where n is 1 is available from Sigma-Aldrich Corporation. The compound (5) where n is 7 and so forth is synthesized according to the method described in U.S. Pat. No. 3,660,505.

Compounds whose synthetic methods are not described above can be prepared according to the methods described in books such as Organic Syntheses (John Wiley & Sons, Inc.), Organic Reactions (John Wiley & Sons, Inc.), Comprehensive Organic Synthesis (Pergamon Press), New experimental Chemistry Course (Shin Jikken Kagaku Kouza, in Japanese; Maruzen Co., Ltd.). The composition is prepared according to known methods using the compounds thus obtained. For example, the component compounds are mixed and dissolved in each other by heating.

Eight, use of the composition will be explained. Most of the composition has a minimum temperature of approximately −10° C. or lower, a maximum temperature of approximately 70° C. or higher, and an optical anisotropy in the range of approximately 0.07 to approximately 0.20. A device containing the composition has a large voltage holding ratio. The composition is suitable for an AM device. The composition is suitable especially for an AM device having a transmission type. The composition having an optical anisotropy in the range of approximately 0.08 to approximately 0.25, and the composition having an optical anisotropy also in the range of approximately 0.10 to approximately 0.30 may be prepared by adjusting ratios of the component compounds or by mixing with any other liquid crystal compound. The composition can be used as a composition having a nematic phase and as an optically active composition by adding an optically active compound.

The composition can be used for an AM device. It can also be used for a PM device. The composition can also be used for the AM device and the PM device having a mode such as PC, TN, STN, ECB, OCB, IPS, VA or PSA. It is especially desirable to use the composition for the AM device having the TN, OCB or IPS mode. These devices may be of a reflection type, a transmission type or a semi-transmission type. It is desirable to use the composition for a device having the transmission type. It can be used for an amorphous silicon-TFT device or a polycrystal silicon-TFT device. The composition is also usable for a nematic curvilinear aligned phase (NCAP) device prepared by microcapsulating the composition, and for a polymer dispersed (PD) device in which a three-dimensional network-polymer is formed in the composition.

Last, members used for the liquid crystal display device will be explained. The liquid crystal display device has a pair of substrates in which at least one of them is transparent, contains a liquid crystal composition sandwiched in between these substrates and has an alignment layer, a polarizing plate and a transparent electrode. For example, the display device has two glass plates that are referred to as an array substrate and a color filter substrate, where a thin-film transistor (TFT), a pixel, a colored layer and so forth are formed on each of the glass substrates. The liquid crystal composition is poured into the space between the two glass substrates, and thus constitutes the liquid crystal display device.

For example, aluminosilicate glass or alumino-borosilicate glass is used as a glass substrate.

An aligning agent used for the alignment layer is not especially limited when it induces orientation to liquid crystal molecules by means of the rubbing treatment which gives orientation, and an illustrative example includes polyimide, polyamide, polyamideimide, polyvinyl alcohol, polyester, polycarbonate, polyamic acid that is a precursor of polyimide, and so fort, or those modified with a material that maintains or reinforce the orientational characteristics. Polyimide, polyamic acid or polyvinyl alcohol is especially desirable.

The polarizing plate is obtained, for example, by the adsorption orientation of iodine molecules to a polyvinyl alcohol (PVA) film that is uniaxially stretched in the direction which is the same with the stretching direction.

Indium-tin oxide or indium-zinc oxide is generally used for the transparent electrode.

EXAMPLES

A composition and a compound were a subject for measurement in order to evaluate characteristics of the composition and the compound to be included in the composition. When the subject for measurement was a composition, the composition itself was measured as a sample, and the value obtained was described here. When a subject for measurement was a compound, a sample for measurement was prepared by mixing 15% by weight of the compound and 85% by weight of mother liquid crystals. The characteristic values of the compound were calculated from values obtained by measurement, according to a method of extrapolation. That is: (extrapolated value)=[(measured value of a sample for measurement)−0.85×(measured value of mother liquid crystals)]/0.15. When a smectic phase (or crystals) separated out in this ratio at 25° C., the ratio of the compound to the mother liquid crystals was changed step by step in the order of (10% by weight/90% by weight), (5% by weight/95% by weight) and (1% by weight/99% by weight). The values of the maximum temperature, the optical anisotropy, the viscosity and the dielectric anisotropy with regard to the compound were obtained by this extrapolation method.

The components of the mother liquid crystals were as follows. The ratios were expressed as a percentage by weight.

Characteristics were measured according to the following methods. Most are methods described in the Standards of Electronic Industries Association of Japan, EIAJ•ED-2521 A, or the modified methods.

Maximum Temperature of a Nematic Phase (NI; ° C.): A sample was placed on a hot plate in a melting point apparatus equipped with a polarizing microscope and was heated at the rate of 1° C. per minute. The temperature was measured when part of the sample began to change from a nematic phase to an isotropic liquid. A higher limit of the temperature range of a nematic phase may be abbreviated to “the maximum temperature.”

Minimum Temperature of a Nematic Phase (Tc; ° C.): A sample having a nematic phase was put in glass vials and then kept in freezers at temperatures of 0° C., −10° C., −20° C., −30° C. and −40° C. for 10 days, and then the liquid crystal phases were observed. For example, when the sample maintained the nematic phase at −20° C. and changed to crystals or a smectic phase at −30° C., Tc was expressed as ≦−20° C. A lower limit of the temperature range of a nematic phase may be abbreviated to “the minimum temperature.”

Viscosity (bulk viscosity; η; measured at 20° C.; mPa·s): Viscosity was measured by use of an E-type viscometer.

Viscosity (rotational viscosity; γ1; measured at 25° C.; mPa·s): Measurement was carried out according to the method described in M. Imai, et al., Molecular Crystals and Liquid Crystals, Vol. 259, 37 (1995). A sample was poured into a TN device in which the twist angle was 0 degrees and the distance between the two glass substrates (cell gap) was 5 micrometers. A voltage with an increment of 0.5 V in the range of 16 V to 19.5 V was applied stepwise to the device. After a period of 0.2 second with no voltage, a voltage was applied repeatedly under the conditions of only one rectangular wave (rectangular pulse; 0.2 second) and of no voltage (2 seconds). The peak current and the peak time of the transient current generated by the applied voltage were measured. The value of rotational viscosity was obtained from the measured values and the calculating equation (8) on page 40 of the paper presented by M. Imai, et al. The value of dielectric anisotropy necessary for this calculation was obtained by use of the device that had been used for the measurement of this rotational viscosity, according to the method that will be described below.

Optical Anisotropy (refractive index anisotropy; Δn; measured at 25° C.): Measurement was carried out by use of an Abbe refractometer with a polarizing plate mounted on the ocular, using light at a wavelength of 589 nanometers. The surface of the main prism was rubbed in one direction, and then a sample was dropped on the main prism. A refractive index (n∥) was measured when the direction of polarized light was parallel to that of the rubbing. A refractive index (n⊥) was measured when the direction of polarized light was perpendicular to that of the rubbing. The value of optical anisotropy was calculated from the equation: Δn=n∥−n⊥.

Dielectric Anisotropy (Δ∈; measured at 25° C.): A sample was poured into a TN device in which the distance between the two glass substrates (cell gap) was 9 micrometers and the twist angle was 80 degrees. Sine waves (10 V, 1 kHz) were applied to this device, and a dielectric constant (∈∥) in the major axis direction of liquid crystal molecules was measured after 2 seconds. Sine waves (0.5 V, 1 kHz) were applied to the device and a dielectric constant (∈⊥) in the minor axis direction of the liquid crystal molecules was measured after 2 seconds. The value of dielectric anisotropy was calculated from the equation: Δ∈=∈∥−∈⊥.

Frequency Dependence of Dielectric Anisotropy (Δ∈ at 5 kHz/Δ∈ at 50 Hz; at −20° C.): A sample was poured into a TN device in which the distance between two glass substrates (cell gap) was (0.5/Δn) micrometers and the twist angle was 80 degrees. The symbol Δn was the value of optical anisotropy measured by the method described above. The device was cooled at −20° C., sine waves (10 V, 5 kHz) were applied to the device, and then a dielectric constant (∈∥) in the major axis direction of liquid crystal molecules was measured. Sine waves (0.5 V, 5 kHz) were applied to the device, and a dielectric constant (∈⊥) in the minor axis direction of liquid crystal molecules was measured. The value of dielectric anisotropy (Δ∈ at 5 kHz) was calculated from the equation: Δ∈=∈∥−∈⊥. Next, sine waves (50 Hz) were applied to the device, and the value of dielectric anisotropy (Δ∈ at 50 Hz) was obtained in a similar manner. The frequency dependence of the dielectric anisotropy was the ratio of these values. When the ratio is close to 1 (one), the frequency dependence is small, that is to say, the frequency dependence is excellent. The frequency dependence of the dielectric anisotropy may occasionally be abbreviated to “the frequency dependence.”

Threshold Voltage (Vth; measured at 25° C.; V): Measurement was carried out with an LCD evaluation system Model LCD-5100 made by Otsuka Electronics Co., Ltd. The light source was a halogen lamp. A sample was poured into a TN device having a normally white mode, in which the distance between the two glass substrates (cell gap) was about 0.45/Δn (micrometers) and the twist angle was 80 degrees. Voltage to be applied to the device (32 Hz, rectangular waves) was stepwise increased in 0.02 V increments from 0 V up to 10 V. During the increase, the device was irradiated with light in the perpendicular direction, and the amount of light passing through the device was measured. A voltage-transmittance curve was prepared, in which the maximum amount of light corresponded to 100% transmittance and the minimum amount of light corresponded to 0% transmittance. The threshold voltage was voltage at 90% transmittance.

Voltage Holding Ratio (VHR-1; measured at 25° C.; %): A TN device used for measurement had a polyimide-alignment film, and the distance between the two glass substrates (cell gap) was 5 micrometers. A sample was poured into the device, and then the device was sealed with a UV-polymerizable adhesive. A pulse voltage (60 microseconds at 5 V) was applied to the TN device and the device was charged. A decreasing voltage was measured for 16.7 milliseconds with a high-speed voltmeter, and the area A between the voltage curve and the horizontal axis in a unit cycle was obtained. The area B was an area without the decrease. The voltage holding ratio was the percentage of the area A to the area B.

Voltage Holding Ratio (VHR-2; measured at 80° C.; %): A TN device used for measurement had a polyimide-alignment film, and the distance between the two glass substrates (cell gap) was 5 micrometers. A sample was poured into the device, and then the device was sealed with a UV-polymerizable adhesive. A pulse voltage (60 microseconds at 5 V) was applied to the TN device and the device was charged. A decreasing voltage was measured for 16.7 milliseconds with a high-speed voltmeter and the area A between the voltage curve and the horizontal axis in a unit cycle was obtained. The area B was an area without the decrease. The voltage holding ratio was a percentage of the area A to the area B.

Voltage Holding Ratio (VHR-3; measured at 25° C.; %): The stability to ultraviolet light was evaluated by measuring a voltage holding ratio after irradiation with ultraviolet light. A composition having a large VHR-3 has a high stability to ultraviolet light. A TN device used for measurement had a polyimide-alignment film and the cell gap was 5 micrometers. A sample was poured into this device, and then the device was irradiated with light for 20 minutes. The light source was an ultra high-pressure mercury lamp USH-500D (produced by Ushio, Inc.), and the distance between the device and the light source was 20 centimeters. In the measurement of VHR-3, a decreasing voltage was measured for 16.7 milliseconds. The value of VHR-3 is preferably 90% or more, and more preferably 95% or more.

Voltage Holding Ratio (VHR-4; measured at 25° C.; %): A TN device into which a sample was poured was heated in a constant-temperature bath at 80° C. for 500 hours, and then the stability to heat was evaluated by measuring the voltage holding ratio. A composition having a large VHR-4 has a high stability to heat. In the measurement of VHR-4, a decreasing voltage was measured for 16.7 milliseconds.

Response Time (τ; measured at 25° C.; millisecond): Measurement was carried out with an LCD evaluation system Model LCD-5100 made by Otsuka Electronics Co., Ltd. The light source was a halogen lamp. The low-pass filter was set at 5 kHz. A sample was poured into a TN device having a normally white mode, in which the cell gap between the two glass substrates was 5.0 micrometers and the twist angle was 80 degrees. Rectangular waves (60 Hz, 5 V, 0.5 second) were applied to this device. The device was simultaneously irradiated with light in the perpendicular direction, and the amount of light passing through the device was measured. The maximum amount of light corresponded to 100% transmittance, and the minimum amount of light corresponded to 0% transmittance. Rise time (τr; millisecond) was the time required for a change from 90% to 10% transmittance. Fall time (τf; millisecond) was the time required for a change from 10% to 90% transmittance. The response time was the sum of the rise time and the fall time thus obtained.

Elastic Constant (K; measured at 25° C.; pN): A LCR meter Model HP 4284-A made by Yokokawa Hewlett-Packard, Ltd. was used for measurement. A sample was poured into a homogeneous alignment cell in which the distance between two glass substrates (cell gap) was 20 micrometers. An electric charge of 0 V to 200 V was applied to the cell, and electrostatic capacity and the applied voltage were measured. The measured values of the electric capacity (C) and the applied voltage (V) were fitted to formula (2.98) and formula (2.101) on page 75 of the “Liquid Crystal Device Handbook” (The Nikkan Kogyo Shimbun, Ltd.) and the values of K11 and K33 were obtained from formula (2.99). Next, the value of K22 was calculated from formula (3.18) on page 171 in the same book and the values of K11 and K22 thus obtained. The Elastic constant was the average value of K11, K22 and K33.

Specific Resistance (ρ; measured at 25° C.; Ωcm): A sample of 1.0 milliliter was poured into a vessel equipped with electrodes. DC voltage (10 V) was applied to the vessel, and the DC current was measured after 10 seconds. The specific resistance was calculated from the following equation. (specific resistance)=[(voltage)×(electric capacity of vessel)]/[(DC current)×(dielectric constant in vacuum)].

Gas Chromatographic Analysis: A gas chromatograph Model GC-14B made by Shimadzu Corporation was used for measurement. The carrier gas was helium (2 milliliters per minute). The sample injector and the detector (FID) were set to 280° C. and 300° C., respectively. A capillary column DB-1 (length 30 meters, bore 0.32 millimeter, film thickness 0.25 micrometer, dimethylpolysiloxane as the stationary phase, non-polar) made by Agilent Technologies, Inc. was used for the separation of component compounds. After the column had been kept at 200° C. for 2 minutes, it was further heated to 280° C. at the rate of 5° C. per minute. A sample was dissolved in acetone (0.1% by weight), and 1 microliter of the solution was injected into the sample injector. A recorder used was a Model C—R5A Chromatopac Integrator made by Shimadzu Corporation or its equivalent. The resulting gas chromatogram showed the retention time of peaks and the peak areas corresponding to the component compounds.

Solvents for diluting the sample may also be chloroform, hexane and so forth. The following capillary columns may also be used in order to separate the component compounds: HP-1 (length 30 meters, bore 0.32 millimeter, film thickness 0.25 micrometer) made by Agilent Technologies Inc., Rtx-1 (length 30 meters, bore 0.32 millimeter, film thickness 0.25 micrometer) made by Restek Corporation, and BP-1 (length 30 meters, bore 0.32 millimeter, film thickness 0.25 micrometer) made by SGE International Pty. Ltd. A capillary column CBP1-M50-025 (length 50 meters, bore 0.25 millimeter, film thickness 0.25 micrometer) made by Shimadzu Corporation may also be used for the purpose of avoiding an overlap of peaks of the compounds.

The ratio of the liquid crystal compounds included in the composition may be calculated according to the following method. The liquid crystal compounds are detected by use of a gas chromatograph. The ratio of peak areas in the gas chromatogram corresponds to the ratio (molar ratio) of the liquid crystal compounds. When the capillary columns described above are used, the correction coefficient of respective liquid crystal compounds may be regarded as 1 (one). Accordingly, the ratio (percentage by weight) of the liquid crystal compound can be calculated from the ratio of peak areas.

The invention will be explained in detail by way of Examples. The invention is not limited by Examples described below. The compounds described in Comparative Examples and Examples were expressed as symbols according to the definition in the following Table 3. In Table 3, the configuration of 1,4-cyclohexylene is trans. A parenthesized number next to the symbolized compound in Example corresponds to the number of a compound. The symbol (−) means any other liquid crystal compound. Ratios (percentage) of liquid crystal compounds mean the percentages by weight (% by weight) based on the total weight of the liquid crystal composition. The liquid crystal composition further includes an impurity. Last, the characteristic values of the liquid crystal display device containing the liquid crystal composition are summarized.

TABLE 3 Method of Description of Compounds using Symbols R—(A₁)—Z₁— . . . —Z_(n)—(A_(n))—R′ 1) Left-terminal Group R— Symbol C_(n)H_(2n+1)— n- C_(n)H_(2n+1)O— nO— C_(m)H_(2m+1)OC_(n)H_(2n)— mOn- CH₂═CH— V- C_(n)H_(2n+1)—CH═CH— nV- CH₂═CH—C_(n)H_(2n)— Vn- C_(m)H_(2m+1)—CH═CH—C_(n)H_(2n)— mVn- CF₂═CH— VFF- CF₂═CH—C_(n)H_(2n)— VFFn- 2) Right-terminal Group —R′ Symbol —C_(n)H_(2n+1) -n —OC_(n)H_(2n+1) -On —CH═CH₂ -V —CH═CH—C_(n)H_(2n+1) -Vn —C_(n)H_(2n)—CH═CH₂ -nV —C_(m)H_(2m)—CH═CH—C_(n)H_(2n+1) -mVn —CH═CF₂ -VFF —F —F —Cl —CL —OCF₃ —OCF3 —CN —C 3) Bonding Group —Z_(n)— Symbol —C₂H₄— 2 —COO— E —CH═CH— V —C≡C— T 4) Ring Structure —A_(n)— Symbol

H

B

B(F)

B(2F)

B(F,F)

B(2F,5F)

Py

dh

G 5) Examples of Description Example 1. 3-HB-CL

Example 2. 3-BB(F)B(F,F)-F

Example 3. 1V-HH-2V1

Example 4. 3-HHB-1

Comparative Example 1

Example 3 was selected from the compositions disclosed in JP S57-154135 A (1982). The basis of the selection was that the composition included the compound (1-11-1). The components and characteristics of the composition were as follows. This composition was prepared, and measured according to the method described above, since there had been no descriptions with regard to K and K/η.

3-HB-C (—) 22.4% 5-HB-C (—) 33.6% 7-HB-C (—) 24% 3-HHB(F)-F (1-11-1) 20%

NI=61.5° C.; Tc≦−15° C.; Δ∈=9.3; Vth=1.58 V; η=23.0 mPa·s; K=12.0 pN; K/η=0.52 nN/Pa·s (nm²/s).

Comparative Example 2

Example 4 was selected from the compositions disclosed in JP S57-185230 A (1982). The basis of the selection was that the composition included the compound (1-23-1). The components and characteristics of the composition were as follows. This composition was prepared, and measured according to the method described above, since there had been no descriptions with regard to K and K/η.

3-HB-C (—) 23.4% 5-HB-C (—) 31.5% 7-HB-C (—) 23.4% 5-HBB-C (—) 11.7% 3-HBB(F)-F (1-23-1) 10%

NI=72.3° C.; Tc≦−6° C.; Vth=1.69 V; η=27.6 mPa·s; K=12.6 pN; K/η=0.46 nN/Pa·s (nm²/s).

Comparative Example 3

Application Example 1 was selected from the compositions disclosed in JP H02-233626 A (1990). The basis of the selection was that the composition included the compound (1-3-1) and the compound (1-11-1). The components and characteristics of the composition were as follows. This composition was prepared, and measured according to the method described above, since there had been no descriptions with regard to K and K/η.

5-HB(F,F)-F (1-3-1) 15% 2-HHB(F)-F (1-11-1) 28.33% 3-HHB(F)-F (1-11-1) 28.33% 5-HHB(F)-F (1-11-1) 28.33%

NI=77.7° C.; Vth=1.94 V; η=17.9 mPa·s; K=11.4 pN; K/η=0.64 nN/Pa·s (nm²/s).

Comparative Example 4

Example A was selected from the compositions disclosed in JP H04-501575 A (1992). The basis of the selection was that the composition included the compound (1), the compound (1-8-1), the compound (1-12-1) and the compound (1-23-1) and had the smallest viscosity. The components and characteristics of the composition were as follows. This composition was prepared, and measured according to the method described above, since there had been no descriptions with regard to K and K/η.

5-HB-F (1) 10% 6-HB-F (1) 7% 7-HB-F (1) 15% 2-HHB-OCF3 (1-8-1) 10% 3-HHB-OCF3 (1-8-1) 12% 4-HHB-OCF3 (1-8-1) 8% 5-HHB-OCF3 (1-8-1) 12% 3-HHB(F,F)-F (1-12-1) 10% 3-HBB(F)-F (1-23-1) 16%

NI=64.0° C.; Δn=0.080; Vth=1.61 V; η=14.0 mPa·s; K=9.4 pN; K/η=0.67 nN/Pa·s (nm²/s).

Comparative Example 5

Example A was selected from the compositions disclosed in JP H04-501576 A (1992). The basis of the selection was that the composition included the compound (1), the compound (1-8-1), the compound (1-23-1) and the compound (2-10-1). The components and characteristics of the composition were as follows. This composition was prepared, and measured according to the method described above, since there had been no descriptions with regard to K and K/η.

5-HB-F (1) 8% 6-HB-F (1) 6% 7-HB-F (1) 5% 2-HHB-OCF3 (1-8-1) 6% 3-HHB-OCF3 (1-8-1) 9% 4-HHB-OCF3 (1-8-1) 6% 5-HHB-OCF3 (1-8-1) 9% 3-HBB(F)-F (1-23-1) 9% 5-HBB(F)-F (1-23-1) 8% 3-HH2B-OCF3 (1) 4% 5-HH2B-OCF3 (1) 4% 3-HB(F)BH-3 (2-10-1) 2% 5-HB(F)BH-3 (2-10-1) 2% 5-HB(F)BH-5 (2-10-1) 2% 3-HHB(F)B-OCF3 (1) 10% 3-HHB(F)B-F (1) 10%

NI=92.0° C.; Vth=2.4 V; η=14.0 mPa·s; K=11.7 pN; K/η=0.48 nN/Pa·s (nm²/s).

Comparative Example 6

Example 5 was selected from the compositions disclosed in JP H04-505477 A (1992). The basis of the selection was that the composition included the compound (1), the compound (1-8-1), the compound (1-12-1) and the compound (1-23-1) and had the smallest viscosity. The components and characteristics of the composition were as follows. This composition was prepared, and measured according to the method described above, since there had been no descriptions with regard to K and K/η.

5-HB-F (1) 11% 6-HB-F (1) 10% 7-HB-F (1) 16% 2-HHB-OCF3 (1-8-1) 9% 3-HHB-OCF3 (1-8-1) 12% 4-HHB-OCF3 (1-8-1) 7% 5-HHB-OCF3 (1-8-1) 12% 3-HBB(F)-F (1-23-1) 10% 5-HBB(F)-F (1-23-1) 13%

NI=60.0° C.; Δn=0.084; Vth=1.61 V; η=12.0 mPa·s; K=8.8 pN; K/η=0.73 nN/Pa·s (nm²/s).

Comparative Example 7

Example 1 was selected from the compositions disclosed in JP H05-105876 A (1993). The basis of the selection was that the composition included the compound (1), the compound (1-8-1), the compound (1-12-1), the compound (1-15-1) and the compound (1-24-1) and had the smallest viscosity. The components and characteristics of the composition were as follows. This composition was prepared, and measured according to the method described above, since there had been no descriptions with regard to K and K/η.

5-HB-F (1) 5% 7-HB-F (1) 5% 2-HHB-OCF3 (1-8-1) 7% 3-HHB-OCF3 (1-8-1) 7% 4-HHB-OCF3 (1-8-1) 7% 5-HHB-OCF3 (1-8-1) 8% 3-HH2B(F)-F (1-15-1) 8% 5-HH2B(F)-F (1-15-1) 8% 3-HBB(F,F)-F (1-24-1) 14% 5-HBB(F,F)-F (1-24-1) 13% 3-HHB(F,F)-F (1-12-1) 9% 5-HHB(F,F)-F (1-12-1) 9%

NI=85.0° C.; Δn=0.092; Vth=1.58 V; η=18.0 mPa·s; K=11.0 pN; K/η=0.61 nN/Pa·s (nm²/s).

Example 1

3-HHB(F,F)-F (1-12-1) 10% 4-HHB(F,F)-F (1-12-1) 6% 5-HHB(F,F)-F (1-12-1) 6% 3-HBB(F,F)-F (1-24-1) 30% 2-HHBB(F,F)-F (1-39-1) 2% 3-HHBB(F,F)-F (1-39-1) 4% 4-HHBB(F,F)-F (1-39-1) 3% 1V-HH-V (2-1-1) 11% V-HH-2V (2-1-1) 14% V2-HH-2V (2-1-1) 6% V2-HHB-1 (2-5-1) 4% 3-HHEBH-3 (2-8-1) 4%

NI=94.4° C.; Tc≦−20° C.; Δn=0.097; Δ∈=5.7; Vth=1.71 V; η=15.7 mPa·s; γ1=90.4 mPa·s; K=15.4 pN; K/η=0.98 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.54; VHR-1=99.1%; VHR-2=97.9%; VHR-3=98.2%.

Example 2

3-HHB(F,F)-F (1-12-1) 10% 3-HBB(F,F)-F (1-24-1) 40% 2-HHBB(F,F)-F (1-39-1) 4% 3-HHBB(F,F)-F (1-39-1) 4% 4-HHBB(F,F)-F (1-39-1) 3% V-HH-3 (2-1-1) 15% 1V-HH-V (2-1-1) 10% 1V2-HH-V1 (2-1-1) 5% 1V2-HH-2V1 (2-1-1) 3% V-HHB-1 (2-5-1) 3% 2-BB(F)B-3 (2-7-1) 3%

NI=77.5° C.; Tc≦−20° C.; Δn=0.102; Δ∈=5.6; Vth=1.64 V; η=13.8 mPa·s; γ1=64.4 mPa·s; K=13.3 pN; K/η=0.96 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.55; VHR-1=99.0%; VHR-2=98.1%; VHR-3=98.0%.

Example 3

3-HB-CL (1-1-1) 10% 3-HHB-CL (1-7-1) 4% 3-HHB(F)-F (1-11-1) 7% 3-HBB(F,F)-F (1-24-1) 25% 3-HHEBB-F (1-37-1) 3% 3-HH2BB(F,F)-F (1-41-1) 6% 4-HH2BB(F,F)-F (1-41-1) 4% 1V-HH-3 (2-1-1) 8% V-HH-V (2-1-1) 10% V-HH-2V (2-1-1) 15% 3-HBB-2 (2-6-1) 3% 1-BB(F)B-2V (2-7-1) 5%

NI=86.4° C.; Tc≦−20° C.; Δn=0.109; Δ∈=4.3; Vth=1.91 V; η=12.7 mPa·s; γ1=52.4 mPa·s; K=13.4 pN; K/η=1.06 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.53; VHR-1=99.1%; VHR-2=98.0%; VHR-3=98.1%.

Example 4

1V2-BB-CL (1) 3% 7-HB(F)-F (1-2-1) 5% 7-HB(F,F)-F (1-3-1) 7% 3-HHB(F,F)-F (1-12-1) 10% 3-H2HB(F)-F (1-13-1) 5% 5-H2HB(F)-F (1-13-1) 5% 3-H2HB(F,F)-F (1-14-1) 6% 4-H2HB(F,F)-F (1-14-1) 5% 3-HH2B(F,F)-F (1-16-1) 12% 3-HBB-F (1-22-1) 5% V-HH-5 (2-1-1) 9% 1V-HH-V (2-1-1) 8% V2-HH-2V (2-1-1) 8% V2-BB(F)B-1 (2-7-1) 4% 5-HBB(F)B-3 (2-11-1) 8%

NI=75.0° C.; Tc≦−20° C.; Δn=0.090; Δ∈=4.5; Vth=1.88 V; η=13.7 mPa·s; γ1=63.4 mPa·s; K=13.7 pN; K/η=1.00 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.63; VHR-1=99.0%; VHR-2=98.0%; VHR-3=98.0%.

Example 5

5-H2B(F)-F (1-4-1) 7% 3-HHB-OCF3 (1-8-1) 10% 3-HHEB-F (1-17-1) 6% 5-HHEB-F (1-17-1) 5% 2-HBEB(F,F)-F (1-30-1) 3% 3-HBEB(F,F)-F (1-30-1) 4% 3-BB(F,F)B(F)-OCF3 (1-32-1) 8% 3-BBB(F,F)-F (1-33-1) 3% 3-BB2B(F,F)-F (1-36-1) 3% V-HH-3 (2-1-1) 16% V-HH-2V (2-1-1) 15% 1V2-HH-V (2-1-1) 5% V-HHB-1 (2-5-1) 6% 5-HBBH-3 (2-9-1) 3% 5-HB(F)BH-3 (2-10-1) 6%

NI=91.0° C.; Tc≦−20° C.; Δn=0.097; Δ∈=4.9; Vth=1.89 V; η=13.9 mPa·s; γ1=64.4 mPa·s; K=14.7 pN; K/η=1.06 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.55; VHR-1=99.1%; VHR-2=98.1%; VHR-3=98.0%.

Example 6

5-HEB-F (1-5-1) 3% 5-HEB(F,F)-F (1-6-1) 5% 3-HHB-F (1-9-1) 5% 2-HHEB(F,F)-F (1-18-1) 4% 3-HHEB(F,F)-F (1-18-1) 8% 3-HBB(F)-F (1-23-1) 9% 5-HBB(F)-F (1-23-1) 6% 5-HBEB-F (1-29-1) 4% 2-BB(F)B(F,F)-F (1-34-1) 4% 3-BB(F)B(F,F)-F (1-34-1) 10% 3-HHBB(F)-F (1-38-1) 4% 5-HHBB(F)-F (1-38-1) 4% 3-HH-O1 (2-1) 3% 3-HH-4 (2-1-1) 3% 1V-HH-V (2-1-1) 8% V-HH-V (2-1-1) 10% V-HH-2V (2-1-1) 10%

NI=78.4° C.; Tc≦−20° C.; Δn=0.101; Δ∈=5.8; Vth=1.64 V; η=14.4 mPa·s; γ1=70.1 mPa·s; K=13.4 pN; K/η=0.93 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.60; VHR-1=98.9%; VHR-2=98.0%; VHR-3=97.9%.

Example 7

3-HHB(F)-OCF3 (1-10-1) 7% 3-HBB(F,F)-F (1-24-1) 12% 2-HB(F)B(F,F)-F (1-25-1) 4% 3-HB(F)B(F,F)-F (1-25-1) 12% 3-H2BB(F,F)-F (1-27-1) 5% 3-HHB(F)B(F,F)-F (1-40-1) 4% 5-HHB(F)B(F,F)-F (1-40-1) 3% 1V2-HH-V (2-1-1) 6% 1V-HH-V (2-1-1) 8% V-HH-2V (2-1-1) 12% 3-HB-O2 (2-2-1) 6% 3-HHEH-5 (2-4-1) 3% VFF-HHB-1 (2-5) 10% 3-HHB-1 (2-5-1) 4% 1V-HBB-2 (2-6-1) 4%

NI=82.9° C.; Tc≦−20° C.; Δn=0.103; Δ∈=5.9; Vth=1.67 V; η=13.6 mPa·s; γ1=63.8 mPa·s; K=13.9 pN; K/η=1.02 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.54; VHR-1=99.0%; VHR-2=97.9%; VHR-3=98.2%.

Example 8

3-HHB(F,F)-F (1-12-1) 10% 3-HH2B(F)-F (1-15-1) 8% 3-H2BB(F)-F (1-26-1) 7% 3-HB(F)EB-OCF3 (1-28-1) 8% 3-HH2BB(F,F)-F (1-41-1) 4% 4-HH2BB(F,F)-F (1-41-1) 4% 1V2-HH-V (2-1-1) 6% 1V-HH-V (2-1-1) 8% V-HH-2V (2-1-1) 16% 7-HB-1 (2-2-1) 3% V2-BB-1 (2-3-1) 4% 1V2-BB-1 (2-3-1) 6% 3-HHB-O1 (2-5-1) 4% V2-HHB-1 (2-5-1) 6% 1-BB(F)B-2V (2-7-1) 6%

NI=91.7° C.; Tc≦−20° C.; Δn=0.111; Δs=4.3; Vth=2.05 V; η=11.2 mPa·s; γ1=51.7 mPa·s; K=13.4 pN; K/η=1.20 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.54; VHR-1=99.0%; VHR-2=98.1%; VHR-3=98.0%.

Example 9

3-HGB(F,F)-F (1-19-1) 3% 3-H2GB(F,F)-F (1-20-1) 5% 5-GHB(F,F)-F (1-21-1) 10% 3-HBB(F,F)-F (1-24-1) 10% 2-HHBB(F,F)-F (1-39-1) 3% 3-HHBB(F,F)-F (1-39-1) 4% 3-HH-VFF (2-1) 9% 1V-HH-3 (2-1-1) 6% V-HH-V (2-1-1) 10% V-HH-2V (2-1-1) 11% 1V2-BB-1 (2-3-1) 4% V-HHB-1 (2-5-1) 7% 1-BB(F)B-2V (2-7-1) 5% 2-BB(F)B-2V (2-7-1) 5% 3-HHEBH-5 (2-8-1) 4% 1O1-HBBH-5 (—) 4%

NI=95.3° C.; Tc≦−20° C.; Δn=0.110; Δ∈=5.5; Vth=1.81 V; η=13.8 mPa·s; γ1=64.5 mPa·s; K=14.2 pN; K/η=1.03 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.54; VHR-1=99.1%; VHR-2=98.1%; VHR-3=98.1%.

Example 10

1-BB(F)B-2V (2-7-1) 5% 3-HBB(F,F)-F (1-24-1) 20% 3-BB(F)B(F,F)-F (1-34-1) 8% V-HH-3 (2-1-1) 15% V-HH-V (2-1-1) 10% V-HH-2V (2-1-1) 10% V2-HHB-1 (2-5-1) 5% 5-HBB(F)B-3 (2-11-1) 4% 3-H2HB(F,F)-F (1-14-1) 6% 3-BB(F,F)B-F (1-31-1) 4% 3-B2BB(F,F)-F (1-35-1) 5% 3-HHB(F)B(F,F)-F (1-40-1) 4% 3-HH2BB(F,F)-F (1-41-1) 4%

NI=80.3° C.; Tc≦−20° C.; Δn=0.118; Δ∈=6.0; Vth=1.60 V; η=14.3 mPa·s; γ1=67.9 mPa·s; K=13.8 pN; K/η=0.97 nN/Pa·s (nm²/s); Δ∈(5 kHz)/Δ∈(50 Hz)=0.56; VHR-1=99.1%; VHR-2=98.1%; VHR-3=98.2%.

The liquid crystal compositions used for the liquid crystal display devices in Example 1 to Example 10 have a large elastic constant in comparison with those in Comparative Examples 1 to 7. Thus, the liquid crystal compositions used for the liquid crystal display device of the invention are so much superior in characteristics to the liquid crystal compositions used for the liquid crystal display devices shown in the patent documents No. 1 to No. 7.

Industrial Applicability

The invention provides a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or that is suitably balanced regarding at least two of the characteristics. A liquid crystal display device containing such a liquid crystal composition becomes an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth, and thus it can be used for a liquid crystal projector, a liquid crystal television and so forth. 

What is claimed is:
 1. A liquid crystal display device having a pair of substrates in which at least one of them is transparent, containing a liquid crystal composition sandwiched in between these substrates and having an alignment layer, a polarizing plate and a transparent electrode, wherein the liquid crystal composition has positive dielectric anisotropy, an elastic constant (K) is 13 pN or more, and the ratio of the elastic constant (K) to the viscosity (η) is 0.8 nN/Pa·s (nm²/s) or more and includes at least one compound selected from the group of compounds represented by formula (1) as a first component:

wherein R¹ is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring A is independently tetrahydropyran-2,5-diyl, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine; Z¹ is independently a single bond, ethylene or carbonyloxy; X¹ and X² are independently hydrogen or fluorine; Y¹ is fluorine, chlorine or trifluoromethoxy; and m is 1, 2 or 3; and at least one compound selected from the group of compounds represented by formula (2) as a second component:

wherein R² and R³ are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring B and the ring C are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z² is independently a single bond, ethylene or carbonyloxy; and p is 1, 2 or
 3. 2. The liquid crystal display device according to claim 1, wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-1) to formula (1-41):

wherein R¹ is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
 3. The liquid crystal display device according to claim 2, wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-1).
 4. The liquid crystal display device according to claim 2, wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-11).
 5. The liquid crystal display device according to claim 2, wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-12).
 6. The liquid crystal display device according to claim 2, wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-22).
 7. The liquid crystal display device according to claim 2, wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-23).
 8. The liquid crystal display device according to claim 2, wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-24).
 9. The liquid crystal display device according to claim 2, wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-34).
 10. The liquid crystal display device according to claim 2, wherein the first component of the liquid crystal composition is a mixture of at least one compound selected from the group of compounds represented by formula (1-12) and at least one compound selected from the group of compounds represented by formula (1-24).
 11. The liquid crystal display device according to claim 1, wherein the ratio of the first component of the liquid crystal composition is in the range of 10% by weight to 70% by weight based on the total weight of the liquid crystal composition.
 12. The liquid crystal display device according to claim 1, wherein the second component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-11):

wherein R² and R³ are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
 13. The liquid crystal display device according to claim 12, wherein the second component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (2-1).
 14. The liquid crystal display device according to claim 1, wherein the ratio of the second component of the liquid crystal composition is in the range of 30% by weight to 90% by weight based on the total weight of the liquid crystal composition.
 15. The liquid crystal display device according to claim 1, wherein an operating mode of the liquid crystal display device is a TN mode, an OCB mode, an IPS mode or a PSA mode, and a driving mode of the liquid crystal display device is an active matrix mode.
 16. A liquid crystal composition contained in the liquid crystal display device according to claim
 1. 17. The liquid crystal composition according to claim 16, wherein the frequency dependence of the dielectric anisotropy [Δ∈(5 kHz)/ Δ∈(50 Hz)] at −20° C. is 0.50 or more.
 18. The liquid crystal composition according to claim 16, wherein the maximum temperature of a nematic phase is 70° C. or higher, the optical anisotropy (25° C.) at a wavelength of 589 nanometers is 0.08 or more, and the dielectric anisotropy (25° C.) at a frequency of 1 kHz is 2 or more.
 19. The liquid crystal composition according to claim 16, consisting essentially of the first component and the second component.
 20. Use of the liquid crystal composition according to claim 16 in a liquid crystal display device. 